The Natural Geochemistry of Our Environment

Understanding the chemical processes that shape our planet and sustain life

Earth Science Chemistry Environment

Introduction to Environmental Geochemistry

Environmental geochemistry examines the chemical composition of Earth's systems and the natural processes that distribute elements between the atmosphere, hydrosphere, lithosphere, and biosphere . This field provides fundamental insights into how our planet functions and sustains life.

Did You Know?

Over 99% of Earth's crust is composed of just 8 elements: oxygen, silicon, aluminum, iron, calcium, sodium, potassium, and magnesium .

Geological Time

Many geochemical processes operate on timescales of thousands to millions of years, creating the stable environment necessary for life to evolve .

The study of natural geochemistry helps us understand the baseline conditions of our environment before human influence, providing crucial context for assessing anthropogenic impacts and developing sustainable practices .

Key Elements in Environmental Geochemistry

Certain elements play disproportionately important roles in environmental processes due to their abundance, reactivity, or biological significance .

Major Elements

These elements constitute the bulk of Earth's crust and are fundamental to geological processes:

Oxygen (46.6%) Silicon (27.7%) Aluminum (8.1%) Iron (5.0%) Calcium (3.6%)

Percentage by weight in Earth's continental crust

Biologically Essential Elements

Elements critical for life processes, often required in trace amounts:

Carbon Nitrogen Phosphorus Potassium Iron Zinc

These elements form the building blocks of biomolecules and enable metabolic processes

Major Biogeochemical Cycles

Elements move through Earth's systems in complex cycles that connect biological, geological, and chemical processes . These cycles regulate the availability of essential elements and maintain environmental stability.

Element Cycle Comparison
Carbon Cycle

Regulates climate and provides the fundamental building block for life .

Atmospheric CO₂
Photosynthesis
Respiration/Decomposition
Ocean Uptake
Water Cycle

Distributes heat and transports elements across the planet .

Evaporation
Condensation
Precipitation
Runoff/Infiltration
Nitrogen Cycle

Converts atmospheric nitrogen into biologically usable forms .

Nitrogen Fixation
Nitrification
Assimilation
Denitrification

Element Distribution in Earth's Systems

The concentration of elements varies dramatically between different environmental compartments, reflecting their chemical properties and the processes that transport them .

Element Distribution in Earth's Crust
Major Ions in Seawater
Element Mobility in Different Environments
Element Atmosphere Freshwater Ocean Soil Sediment
Oxygen High High High Medium Low
Carbon High High High Medium Low
Iron Low Medium Low Medium High
Silicon Low Medium Medium High High

Mobility ratings indicate the relative ease with which elements move through each environmental compartment

Fundamental Geochemical Processes

Natural geochemical processes transform and redistribute elements, creating the dynamic equilibrium that characterizes Earth's environment .

Weathering

The breakdown of rocks at Earth's surface through physical, chemical, and biological processes .

Physical 40%
Chemical 35%
Biological 25%
  • Temperature changes cause expansion and contraction
  • Water dissolves minerals through hydrolysis
  • Plant roots and lichens physically break apart rocks
Ion Exchange

The reversible interchange of ions between solid and liquid phases, crucial for nutrient availability in soils .

Ca²⁺ 2K⁺
Clay minerals exchange calcium for potassium

This process regulates soil fertility and the availability of essential plant nutrients.

Mineral Precipitation

Formation of solid minerals from dissolved ions, creating sedimentary rocks and regulating ocean chemistry .

Calcite
Halite
Gypsum

When solution becomes supersaturated, minerals precipitate out, forming deposits like limestone, salt flats, and evaporites.

Redox Reactions

Transfer of electrons between chemical species, driving many biogeochemical cycles .

Oxidizing Conditions Reducing Conditions
O₂ Rich
Transition
O₂ Poor

These reactions control the speciation and mobility of elements like iron, manganese, and sulfur in natural systems.

Environmental Implications

Understanding natural geochemistry provides essential context for addressing environmental challenges and managing Earth's resources sustainably .

Natural vs. Anthropogenic Fluxes

Human activities have significantly altered natural biogeochemical cycles, in some cases exceeding natural fluxes .

Carbon Sequestration

Natural processes remove CO₂ from the atmosphere through weathering, photosynthesis, and ocean uptake .

2.6 GtC/year Ocean uptake
Water Purification

Geochemical processes naturally filter and purify water as it moves through soils and aquifers .

Ion Exchange Adsorption Precipitation
Pollution Buffering

Natural systems can buffer against pollution through various geochemical mechanisms .

pH Neutralization Redox Buffering Complexation